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Material Safety Data Sheet

Benedict's Reagent Qualitative Solution

ACC# 90749

Section 1 - Chemical Product and Company Identification

MSDS Name: Benedict's Reagent Qualitative Solution Catalog Numbers: S71369, S71369-1, S713691ND Synonyms: Benedict's Sugar Test Reagent. Company Identification: Fisher Scientific 1 Reagent Lane Fair Lawn, NJ 07410 For information, call: 201-796- Emergency Number: 201-796- For CHEMTREC assistance, call: 800-424- For International CHEMTREC assistance, call: 703-527-

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS 7732-18-5 Water 74 231-791- 68-04-2 Trisodium citrate anhydrous 15 200-675- 497-19-8 Sodium carbonate anhydrous 8 207-838- 7758-98-7 Cupric sulfate 1 231-847-

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: clear light-blue liquid.

Warning! Harmful if swallowed. May cause allergic skin reaction. May cause blood abnormalities. May

cause severe eye and skin irritation with possible burns. May cause respiratory and digestive tract irritation and possible burns. May cause adverse reproductive effects. May cause liver and kidney damage. Target Organs: Blood, kidneys, liver.

Potential Health Effects Eye: May result in corneal injury. Contact with eyes may cause severe irritation, and possible eye burns. Contact with the eye may cause conjunctivitis, edema of the eyelids, and ulceration and turbidity of cornea. Skin: May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Contact with the skin may cause severe irritation and necrosis. May produce eczematoid contact dermatitis. Ingestion: Ingestion of large amounts of copper salts may cause bloody stools and vomit, low blood pressure, jaundice and coma. Ingestion of sodium citrate may produce alkalosis and may cause tetany or depress the heart by decreasing the calcium level of the blood. Ingestion may produce corrosion of the GI tract, vomiting, diarrhea, circulatory collapse, and death. Ingestion of copper compounds may produce systemic toxic effects to the kidney and liver and central nervous excitation followed by depression. Inhalation: Inhalation of fumes may cause metal fume fever, which is characterized by flu-like symptoms with metallic taste, fever, chills, cough, weakness, chest pain, muscle pain and increased white blood cell count. May produce local necrosis of the mucous membranes.

Chronic: Repeated exposure may cause sensitization dermatitis. Individuals with Wilson's disease are unable to metabolize copper. Thus, copper accumulates in various tissues and may result in liver, kidney, and brain damage. Chronic copper poisoning in man is recognized in the form of Wilson's disease. May cause allergic skin reaction in some individuals.

Section 4 - First Aid Measures

Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Substance is nonflammable; use agent most appropriate to extinguish surrounding fire. Flash Point: Not available. Autoignition Temperature: Not available. Explosion Limits, Lower:Not available. Upper: Not available. NFPA Rating: (estimated) Health: 2; Flammability: 0; Instability: 1

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e. vermiculite, sand or earth), then place in suitable container. Provide ventilation. Cover with dry earth, dry sand, or other non-combustible material followed with plastic sheet to minimize spreading and contact with water.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Use adequate ventilation to keep airborne concentrations low.

CAS# 7732-18-5: ZC

CAS# 68-04-2: GE

CAS# 497-19-8: VZ

CAS# 7758-98-7: GL

LD50/LC50:

CAS# 7732-18-5:

Oral, rat: LD50 = >90 mL/kg; .

CAS# 68-04-2: .

CAS# 497-19-8: Draize test, rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, eye: 50 mg Severe; Draize test, rabbit, skin: 500 mg/24H Mild; Inhalation, mouse: LC50 = 1200 mg/m3/2H; Inhalation, rat: LC50 = 2300 mg/m3/2H; Oral, mouse: LD50 = 6600 mg/kg; Oral, mouse: LD50 = 6600 mg/kg; Oral, rat: LD50 = 4090 mg/kg; .

CAS# 7758-98-7: Oral, mouse: LD50 = 369 mg/kg; Oral, mouse: LD50 = 87 mg/kg; Oral, rat: LD50 = 300 mg/kg; Oral, rat: LD50 = 960 mg/kg; .

Carcinogenicity: CAS# 7732-18-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65. CAS# 68-04-2: Not listed by ACGIH, IARC, NTP, or CA Prop 65. CAS# 497-19-8: Not listed by ACGIH, IARC, NTP, or CA Prop 65. CAS# 7758-98-7: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: Experimental reproductive effects and mutation data have been reported for copper sulfate. Teratogenicity: No information found Reproductive Effects: No information found Mutagenicity: No information found Neurotoxicity: No information found Other Studies:

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series: None listed. RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG Shipping Name: Not regulated as a hazardous material No information available. Hazard Class: UN Number: Packing Group:

Section 15 - Regulatory Information

US FEDERAL

TSCA

CAS# 7732-18-5 is listed on the TSCA inventory. CAS# 68-04-2 is listed on the TSCA inventory. CAS# 497-19-8 is listed on the TSCA inventory. CAS# 7758-98-7 is listed on the TSCA inventory. Health & Safety Reporting List None of the chemicals are on the Health & Safety Reporting List. Chemical Test Rules None of the chemicals in this product are under a Chemical Test Rule. Section 12b None of the chemicals are listed under TSCA Section 12b. TSCA Significant New Use Rule None of the chemicals in this material have a SNUR under TSCA. CERCLA Hazardous Substances and corresponding RQs CAS# 7758-98-7: 10 lb final RQ; 4 kg final RQ SARA Section 302 Extremely Hazardous Substances None of the chemicals in this product have a TPQ. SARA Codes CAS # 497-19-8: immediate. CAS # 7758-98-7: immediate. Section 313 This material contains Cupric sulfate (listed as Copper compounds, n.o.), 1%, (CAS# 7758-98-7) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373. Clean Air Act: This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors. Clean Water Act: CAS# 7758-98-7 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. CAS# 7758-98-7 is listed as a Toxic Pollutant under the Clean Water Act. OSHA: None of the chemicals in this product are considered highly hazardous by OSHA. STATE CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ. CAS# 68-04-2 is not present on state lists from CA, PA, MN, MA, FL, or NJ. CAS# 497-19-8 is not present on state lists from CA, PA, MN, MA, FL, or NJ. CAS# 7758-98-7 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Massachusetts.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

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Fscimage.fishersci

Subject: Environmental Science

999+ Documents

Students shared 1761 documents in this course

Level:

Standard

Was this document helpful?

Material Safety Data Sheet

Benedict's Reagent Qualitative Solution

ACC# 90749

Section 1 - Chemical Product and Company Identification

MSDS Name: Benedict's Reagent Qualitative Solution

Catalog Numbers: S71369, S71369-1, S713691ND

Synonyms: Benedict's Sugar Test Reagent.

Company Identification:

Fisher Scientific

1 Reagent Lane

Fair Lawn, NJ 07410

For information, call: 201-796-7100

Emergency Number: 201-796-7100

For CHEMTREC assistance, call: 800-424-9300

For International CHEMTREC assistance, call: 703-527-3887

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS

7732-18-5 Water 74.7 231-791-2

68-04-2 Trisodium citrate anhydrous 15.1 200-675-3

497-19-8 Sodium carbonate anhydrous 8.7 207-838-8

7758-98-7 Cupric sulfate 1.5 231-847-6

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: clear light-blue liquid.

Warning! Harmful if swallowed. May cause allergic skin reaction. May cause blood abnormalities. May

cause severe eye and skin irritation with possible burns. May cause respiratory and digestive tract irritation

and possible burns. May cause adverse reproductive effects. May cause liver and kidney damage.

Target Organs: Blood, kidneys, liver.

Potential Health Effects

Eye: May result in corneal injury. Contact with eyes may cause severe irritation, and possible eye burns.

Contact with the eye may cause conjunctivitis, edema of the eyelids, and ulceration and turbidity of cornea.

Skin: May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this

material. Contact with the skin may cause severe irritation and necrosis. May produce eczematoid contact

dermatitis.

Ingestion: Ingestion of large amounts of copper salts may cause bloody stools and vomit, low blood

pressure, jaundice and coma. Ingestion of sodium citrate may produce alkalosis and may cause tetany or

depress the heart by decreasing the calcium level of the blood. Ingestion may produce corrosion of the GI

tract, vomiting, diarrhea, circulatory collapse, and death. Ingestion of copper compounds may produce

systemic toxic effects to the kidney and liver and central nervous excitation followed by depression.

Inhalation: Inhalation of fumes may cause metal fume fever, which is characterized by flu-like symptoms

with metallic taste, fever, chills, cough, weakness, chest pain, muscle pain and increased white blood cell

count. May produce local necrosis of the mucous membranes.

Fscimage.fishersci

Environmental Science

Standard