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Purification of organic compounds sublimation

Course: ORGANIC CHEMISTRY-I

38 Documents
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University: Amity University

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SUBLIMATION
Some substances when heated, pass directly from the
solid to the vapour state without melting. The vapours
when cooled given back the solid substance. This
process known as sublimation is very helpful in
separating volatile from non-volatile solid. It is,
however, of limited application as only a few
substances like a naphthalene, camphor and benzoic
acid can be purified by this process.
The impure substance is placed in a large beaker. The
beaker is covered with a watch glass. Heat is applied
gently to the beaker, and the resulting vapours
condense as crystals on the bottom surface of the
watch glass. The watch glass can be removed after
sometime and the crystals collected.